Growth of ettringite crystals opens the crack and damages the cement products. Jun 01, 2008 diagnosing delayed ettringite formation in concrete structures diagnosing delayed ettringite formation in concrete structures thomas, michael. This implies that if excessive soluble sulfate contents in cements were available, it would be reasonable to expect field problems in concrete made from that cement to show up relatively early in the life of the structure, probably. Delayed ettringite formation has been a significant problem in many countries. There have been far fewer documented cases of def than of asr, and prior to this project, there were no published cases in which def was the sole culprit in causing deterioration in an actual field structure. Aci committee 201, guide to durable concrete, aci manual of concrete. The disruptive effect is due to the nonuniform expansion localized only in the area of the concrete structure where ettringite forms. Charactherization of delayed ettringite formation in maryland bridges complete project report pdf free download abstract.
Chemical and petrographic analyses and astm test procedures. Expansion results from formation of ettringite crystals of submicrometre size in the paste, the larger. It also occurs as weathering crusts on larnite in the hatrurim formation. Delayed ettringite formation processes and problems. The modernized delayed benoni modernized reti benoni benoni defense modern benoni the modernized reti, a complete repertoire for white 771. Influence of relative humidity on delayed ettringite formation. Delayed ettringite formation in concrete jochen stark, katrin bollmann bauhausuniversity weimar germany 1. Ettringite is also known as c ement bacillus, which is the name of a naturally occurring mineral of the same composition and structure. Delayed ettringite formation def is seen as a form of internal sulfate attack of cementitious materials, caused by early age heating to a temperature higher than 70c. Evaluation for the potential of delayed ettringite formation charts generated by thermocouples cast into the affected concrete measured curing temperatures of significantly in excess of the. At the present time, there is no selective and predictive test for def this paper describes the results of a study aimed at developing a test based on drying and wetting cycles. Claims that slow release of sulfate from the clinker can have a similar effect.
Procedures for quantifying the potential degree of future def development in concrete, using accelerated hydration and dta determination of any additional ettringite developed. Collepardi civil engineering faculty, leonardo da vinci, politechnic milan, italy abstract. Cracks due to delayed ettringite formation civildigital. The effect of the partial cement substitution with fly ash on. Def causes a characteristic form of damage which is highly influenced by the cement chemistry, curing methods and exposure conditions. Reducing expansion due to delayed ettringite formation def is becoming an important issue that. Delayed ettringite formation def in concrete and mortar systems has been associated with deleterious expansion leading to its premature deterioration. The purpose of extending mellowing time before compaction in soils is to force ettringite formation prior to compaction of pavement layers. Qualitative and quantitative analyses for ettringite, including xray diffraction xrd and differential thermal analysis dta.
Civil engineering faculty, leonardo da vinci, politechnic. Ettringite formation and the performance of concrete portland. Delayed ettringite formation def is expansion and cracking of concrete associated with the delayed formation of the mineral ettringite which is a normal product of early cement hydration. Blast furnace slag addition effects on delayed ettringite formation. Mechanisms affecting the delayed efficiency of cement.
Delayed ettringite formation, favored by the high sulfate content of fly ashes and contrasted by the low sulfate content of natural. An experimental clarification of the association of delayed ettringite formation with alkaliaggregate reaction. Pdf delayed ettringite formation in fly ash concrete under moist. Mortars made from cements with sulphate levels of 3%. Characterization of damage in mortar and concrete specimens. Characterization of delayed ettringite formation in maryland bridges.
Study of asraffected and defaffected structures as well as testing and evaluation results of eliminating components. Pdf delayed ettringite formation fami fami academia. Delayed ettringite formation def in concrete is likely to lead to swelling and cracking in structures which have undergone early age heating to a temperature of over 65 c. Characterization of delayed ettringite formation using. A nondestructive acoustic approach for the detection and quantification of damage in mortars affected by delayed ettringite formation def is used to study the degradation mechanism at micro and macroscales. Abstractexpansive internal sulphate reaction of concrete due to delayed ettringite formation def can damage concrete structures severely. Strategies for prevention of delayed ettringite formation in. Delayed ettringite formation is a relatively rare and controversial phenomenon in concrete deterioration, strongly related to the practice of heat curing. Characterization of delayed ettringite formation using nonlinear impact resonance spectroscopy method. Moist map cracking, a suggested defrelated damage, appears to be correlated with lamellar ettringite formations and high quantities of def with in the concrete. A test method to determine the expansion potential, due to delayed ettringite formation def, of portland. The two main chemicals attacks to concrete are attributed to alkaliaggregate reaction aar and the action of sulphates, among which stands out the delayed ettringite formation def delayed ettringite formation. The combination of mellowing time and moisture content that achieves this goal is selected.
Delayed ettringite formation, cement and concrete research. Lehmann, for an occurrence near the ettringer bellerberg volcano, ettringen, rheinlandpfalz, germany. Blast furnace slag addition effects on delayed ettringite. It can take up to 20 years for cracking to become apparent. Delayed ettringite formation def occurs at late ages and the related heterogeneous expansion in a very rigid hardened concrete can produce cracking and spalling. Delayed ettringite formation def delayed ettringite formation def is expansion and cracking of concrete associated with the delayed formation of the mineral ettringite which is a normal product of early cement hydration. Sulfate attack is a complex form of deterioration that has damaged concrete structures throughout the world.
It can affect materials that have experienced temperatures higher than about 65 c at early age. The mechanism of expansion is still the subject of research. The formation of ettringite or cement bacillus has been. May 01, 2001 delayed ettringite formation def can damage concrete that has experienced a temperature above about 70c. Ettringite formation and the performance of concrete.
Delayed ettringite formation def is expansion and cracking of concrete associated with the delayed formation of the mineral ettringite which is a normal product of early cement. In this paper, the effect of fly ash on delayed ettringite formation of heatcured cementbased mortars was investigated. A test method to determine the expansion potential, due to delayed ettringite formation def, of portland cements initially moistcured at high temperatures was developed. Due to the hydration process, temperatures in concrete will increase during early stages and when the temperature exceeds 70 0 c, delayed ettringite formation def can take place. Delayed ettringite formation def in cementitious materials is considered as a harmful chemical reaction leading to a variety of damages. Expansion of cement mortars made with eight different portland cements was investigated. Mineral additives used as partial cement replacement should help in achieving the desired aspect. Download charactherization of delayed ettringite formation in maryland bridges complete project report. Delayed ettringite formation s s s s s s s s a a a a a a a a alumina s sulfate ettringite cement grain csh water water water occurs when fresh concrete is heated above a temperature of 158f.
This delayed ettringite formation may result in the decrease of resistance of portland cement concrete to chloride penetration. Def is a result of high early temperatures above 70 o c 80 o c in the concrete which prevents the normal formation. Examples of sulfate attack include ettringite formation, delayed ettringite formation, and thaumasite formation hobbs, 2001. As discussed above, high content of alkalis will lead to less quantities of early ettringite formed, thus resulting in higher sulphate contents being available for reaction later to form delayed ettringite.
With many large scale civil engineering construction projects being undertaken, there is a possibility to find large concrete pours in thick members. Edges and corners are particularly vulnerable, and a friable concrete surface results figure 8. Mpa cement fact sheet 3 introduction def has caused cracking in some heat cured precast concrete components many years after the concrete was produced. Def is a result of high early temperatures above 70 o c 80 o c in the concrete which prevents the normal formation of ettringite. Pdf charactherization of delayed ettringite formation in. Types and causes of cracking in concrete structures.
The modernized delayed benoni modernized reti benoni benoni defense modern benoni the modernized reti, a. Delayed ettringite formation an overview sciencedirect topics. Precastprestressed concrete institute, manual for quality control. When ettringite forms later after several months or years def the related heterogeneous expansion in a very rigid hardened concrete can produce cracking. Larosche, in failure, distress and repair of concrete structures, 2009. Mathematical modeling of the pessimum action of chlorides. It is a normal product in concrete and is delayed when the temperature rises too high for it to form.
Alkalisilica reaction and delayed ettringite formation. Delayed ettringite formation in portland cement products. This information paper, which is mainly concerned with insitu concrete, identifies the circumstances in which delayed ettringite formation may cause problems. Delayed ettringite formation def is sometimes called an internal sulfate attack. Significance of delayed ettringite formation and damage. Risk analysis of the delayed ettringite formation in pile. Wje was requested to investigate the possible effect of the reported elevated temperature on the durability of this major structure with a 100year design service life. Mathematical modeling of the pessimum action of chlorides on the extent of delayed ettringite formation.
For a pavement that is experiencing accelerated deterioration due to delayed ettringite formation, and that is near a minimum service level condition i. Diagnosing delayed ettringite formation in concrete. Fu, delayed ettringite formation in portland cement products, phd thesis, department of civil engineering, university of ottawa, ottawa, 1996. Formulation pelmane lenge mulongo1,a, stephen ekolu1,b 1cement and. Sulfate attack is particularly complex because the source of sulfates can be external or internal delayed ettringite formation, and the distress can be chemical in nature, due to alteration of hydration of products, or physical in nature, due to phase changes in the penetrating. Based on an ongoing experimental program, this research emphasizes on the effect of blast furnace slag bfs on the expansion of cement. Delayed ettnngite formation def is an endogenous reaction which can cause deterioration in concrete. It is only damaging to concrete cured under low temperatures, where it forms more slowly, or high temperatures which may delay the formation of ettringite. Nondestructive evaluation of inservice concrete structures. Delayed ettringite formation aci concrete code issues. The cause for these failures has been identified as delayed ettringite attack, a process whereby the normal formation of ettringite in plastic portland cement concrete is either delayed or is.
On the delayed expansion of heat cured portland cement pastes and concretes. Controlling ettringite formation recommended practice for. Delayed ettringite formation a concern for precast concrete. When ettringite forms later after several months or years def the related heterogeneous expansion in a very rigid hardened concrete can produce cracking and spalling. Pathology, assessment and treatment of structures affected. The term premature concrete deterioration pcd has been adopted to refer to problems associated with asr and def because it is often difficult to distinguish between them.
Characterization of delayed ettringite formation in maryland. Delayed ettringite formation is a consequence of improper heating during the curing process. Delayed ettringite formation archives civildigital. Claims that slow release of sulfate from the clinker can have a. Mpa cement fact sheet 3 delayed etttringite formation in. Heat curing and delayed ettringite formation mrs online. Delayed ettringite formation def is a chemical reaction with proven damaging effects on the mechanical properties of hydrated cementitious. The effect of delayed ettringite formation on fine grained. Delayed ettringite formation def is a special case of internal sulfate attack. Reducing expansion due to delayed ettringite formation def is becoming an important issue that must be taken into account, when producing heatcured concrete. Accelerated test for measuring sulfate resistance of. The formation of ettringite or cement bacillus has been recognized as the cause of excessive expansion, cracking and even complete disintegration of concrete subjected to intensive sulfate attack. A kinetic model for prediction of cement susceptibility to.
Procedures for quantifying the potential degree of future. The research investigated the significance of delayed ettringite formation def. Pathology, assessment and treatment of structures affected by. Pdf during the hydration of cement, tricalcium aluminate c3a reacts with gypsum and forms ettringite aft. Ettringite or hydrated calcium aluminum sulfate hydroxide ca 6 al 2 so 4 3 oh 12 26h 2 o is formed by the reaction between sulfate ions and the aluminate phases in cement. Delayed ettringite formation an overview sciencedirect. Delayed ettringite formation def can affect the longterm durability of concrete structures by causing cracking and expansion of the material. Water is a critical element in the formation of ettringite. Def is defined as the formation of ettringite in a concrete after setting, and without any external sulphate supply but with water supply. Charactherization of delayed ettringite formation in maryland bridges complete project report pdf.
This delayed ettringite formation may result in the decrease of resistance of portland. Delayed ettringite formation is still an open question. Heat curing and delayed ettringite formation volume 370 m. Ettringite formation and sulfate attack on concrete. Delayed ettringite formation def is a possible autogenous expansive reaction of concrete. Based on the experience of the writer and others, def is to be expected in both steam. High temperature curing of concrete long beach, ca wje.
Delayed ettringite formation def can damage concrete that has experienced a temperature above about 70c. It occurs in concrete which has been cured at elevated temperatures, for example, where steam curing has been used. To fulfil the aim of this study, a portion of cement was replaced by class ffly ash, with three. Significance of delayed ettringite formation and damage mechanisms the primary ettringite formation in the initial stage of the hydration is seen as a positive effect because it read more. It occurs within metamorphically altered limestone adjacent to igneous intrusive rocks or within xenoliths.
The most important form of internal sulfate attack is delayed ettringite formation def. Introduction the problem of durability of concrete with cement as binding material comes more and more to the fore with the increased use of concrete, with the changed production and utilization. Its gradual formation in the cooled, set concrete can lead to expansion and cracking in a process known as delayed ettringite formation def. It has been proposed that def expansion is affected by. The formation of ettringite in the fresh, plastic concrete is the mechanism that controls stiffening.
Damage due to the delayed ettringite formation allegedly occurs when material is exposed to temperatures higher than 70c 3,4. This experimental study aims to determine the effect of relative humidity on concrete expansion due to delayed ettringite formation def, which still remains imperfectly known. Delayed ettringite formation def is a relatively rare reaction in which sulphates within hardened concrete form ettringite leading to expansion and cracking. An external source of sulfur is not required for this type of early pcc deterioration to occur. Investigation of the internal stresses caused by delayed. Delayed ettringite formation def is known as the deterioration phenomenon that occurs in mortar or concrete cured at high temperature. As discussed above, high content of alkalis will lead to less quantities of early ettringite formed, thus. Defrelated expansion of concrete as a function of sulfate. Delayed ettringite formation delayed ettringite formation is a less common, but potentially more damaging, cause of distress than asr. Preventing alkalisilica reaction and delayed ettringite. The volume of the formed def crystals in the hardened concrete is larger than the volume of reactants, which results in forces from the growing crystals acting upon the walls of the crack. In turn, the durability of concrete structures can often be affected by chemical attacks, endangering its performance and safety. Evaluation for the potential of delayed ettringite formation charts generated by thermocouples cast into the affected concrete measured curing temperatures of significantly in excess of the specified maximum temperature limit.